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However, recently in Yang Wang et. Dalrymple's work early work on 26 historic lava flows showed that many of them had excess argon and uk free dating singles not set to zero at the eruption of the volcano. The following is the data from these tests: If the present data are representative, argon of slightly anomalous composition can be expected in approximately one out of three volcanic rocks.
Dalrymple may have a point. It seems like rocks dating within one or two million years cannot be accurately dated by K-Ar techniques just because of the relatively wide ranges of error.
He reasons that the Pb in these samples could only have originated by neutron reactions with Pb and that Pb, therefore, would also be created from Pb by similar reactions:.
Cook 28 then proposes that these effects require corrections to the measured lead isotopic ratios as follows: He presents an equation for making these corrections:.
This calculation is repeated by both Morris 92 and Slusher Cook 28Morris 92and Slusher all note that this ratio is close to the present day production ratio of Pb and Pb from U and U, respectively, and conclude, therefore, that the Katanga ores are very young, not old. For example, Slusher states:.